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Manuals

Algorithm comparison

For processing of 3D spectra, one can afford to chose just about any reconstruction program without focussing on the implementation details. However for 4D, it is important that the method not only produces high quality frequency-domain data, but is also implemented in the resource efficient way.

Here we summarize strengths and pitfalls of several reconstruction methods we tried ourselves.

Method NMR Pipe-based RAM consumption Advantages Disadvantages Time of full reconstruction (Ubiquitin)
SMILE Yes Overly high Supposed to be the fastest and the “best” performing method overall for solution data Won’t run due to the [memory leak] on large spectra (about 40 Gb) (https://groups.io/g/nmrpipe/topic/smile_4d_runs_out_of_memory/106780340) NA
TopSpin CS (MDD) No Medium (?) Integrated into TopSpin, peak-shape agnostic No reconstructed 4D FID written, each change in phasing or window function needs the entire reconstruction repeated. Several hours (including the FT)
hmsIST_4D.com Yes Minimal Peak-shape agnostic; integrated into NMR Pipe GUI Utterly inefficient use of the disk space ( 700+ Gb per spectrum); poorly documented  
hmsIST Yes ~50 GB Fast; Good with overlapped peaks Script-based interface  
SSA No NA Fast and rather simple to set up Apparently more prone to miss peaks than IST implementations Overnight